Electrochemical and spectroscopic study of interfacial interactions between chalcopyrite and typical flotation process reagents

Comparative voltammetry and differential double-layer capacitance studies were performed to evaluate interfacial interactions between chalcopyrite (CuFeS₂) and n-isopropyl xanthate (X) in the presence of ammonium bisulfite/39wt% SO₂ and caustic starch at different pH values. Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy, contact angle measurements, and microflotation tests were used to establish the type and extent of xanthate adsorption as well as the species involved under different mineral surface conditions in this study. The results demonstrate that the species that favor a greater hydrophobicity of chalcopyrite are primarily CuX and S0, whereas oxides and hydroxides of Cu and Fe as well as an excess of starch decrease the hydrophobicity. A conditioning of the mineral surface with ammonium bisulfite/39wt% SO₂ at pH 6 promotes the activation of surface and enhances the xanthate adsorption. However, this effect is diminished at pH ≥ 8, when an excess of starch is added during the preconditioning step.     

Analysis of Pyrolysates for Phenol Formaldehyde Resin by Py-GC/MS

Pyrolysis of phenol formaldehyde resin has been investigated by Pyrolysis Gas Chromatography-Mass Spectroscopy at the different temperatures from 500℃ to 750℃. Its composition of pyrclysates has been analyzed. Several compounds, especially benzene, toluene, p-xylene could only be formed above 500-550℃. Howerver, peak intensities for some pbend derivatives were decreased at the higher temperature. During pyrolysis, for thermo-setting phenol formaldehyde resins, polymeric chain scissions take place as a successive removal of the monomer units from the polymeric chain. The chain scissions are followed by secondary reactions, which leads to a variety of compounds. Addition reactions can also take place among the double-bond compounds during pyrolysis.     

椭圆偏振法研究四方氧化锆对Zr-Sn-Nb合金氧化膜耐腐蚀性能的影响

将经过不同热处理的Zr-Sn-Nb合金样品放在350℃、16．8mol／LPa、0．01mol／LLiOH溶液的高压釜中进行腐蚀。用椭圆偏振法研究氧化膜中的四方氧化锆，发现经过580℃／冷轧／500℃处理的样品在腐蚀42天和190天后氧化膜中的四方氧化锆比其它样品的多。四方氧化锆是影响合金耐腐蚀性能的一个主要因素，四方氧化锆的形成有利于提高合金的耐腐蚀性能。     

Structural Changes of Water Molecules Upon the Reduction of Quinones in The Reaction Center from Rhodobactery Sphaeroides

1 Results The photosynthetic bacterial reaction center (RC) is a membrane protein complex.The RC is composed of three protein subunits and redox components such as bacteriochlorophylls, bacteriopheophytins,and quinones.The RC performs the photochemical electron transfer from the bacteriochlorophyll dimer through a series of electron donor and acceptor molecules to a secondary quinone,QB.QB accepts electrons from a primary quinone,QA,in two sequential electron transfer reactions.The second electron trans...     

红外光谱分析仪管理、使用中的一点体会

主要就多年来自己在红外光谱分析仪管理和使用中的一些体会进行总结 .科学管理、积极推广 ,提高仪器的使用率 ;精心设计实验内容 ,培养学生解谱能力 ;不断学习新技术、新方法 ,努力提高自身水平 ,充分发挥科学仪器在教学、科研及科技开发工作中的作用 .     

Spectroscopic study on the photophysical properties of chlorine substituted tetraphenylporphyrin-histidine and its zinc(Ⅱ)complexes

As the structural analogues of (bacterio)chlorophylls in photosynthetic organisms, porphyrins play an important role in building up artificial photosynthetic systems[13]. In natural photosynthetic pigment-protein complexes,certain amino acid residuals modulate the reactions ofcharge transfer and energy transfer via coordination andother types of interactions with chlorophyll molecules.For instance, in higher-plant photosynthetic reaction cen-ter PSⅡ, the oxidization-reduction system consistin…     

贝壳棱柱层和珍珠层的傅里叶变化红外光谱

运用热重分析和傅里叶变换红外光谱分析技术,对夏夷扇贝棱柱层和珍珠层粉末样品进行温度变化性质研究.研究结果表明,贝壳棱柱层和珍珠层的主要成分均为方解石型碳酸钙,并含有少量有机质和水分,棱柱层有机质含量高于珍珠层.珍珠层和棱柱层样品分别于600℃、700℃发生碳化,所含有机物分别于700℃、800℃发生完全分解,同时热处理前后红外光谱吸收峰的峰形、峰位发生了明显变化,有机质含量的高低与CO32-不对称伸缩振动ν3的峰位负相关,而与CO32-的面内弯曲振动2ν、面外弯曲振动ν4无关.变化表明,热分解前存在生物大分子与方解石型碳酸钙的配位作用,从分子结构水平上揭示了生物矿化材料中有机质对无机晶体的配位作用.     

金属间化合物Ni3Al中的硼晶界偏聚特性的AES研究

本文应用俄歇能谱仪研究了不同化学计量比ＮｉＡｌ金属间化合物硼在晶界偏聚的特性。研究结果表明：硼在Ｎｉ３Ａｌ的各个晶界偏聚存在着不均匀性，硼在晶界的偏聚范围只有几个原子层，晶界结构及晶界化学环境是影响在晶界偏聚的决定因素。     

PS－FeCl_3催化剂结构及活性的MOSSBAUER谱的研究

不同交联度的ＰＳ－ＦｅＣｌ＿３配位化合物的Ｍｓｓｂａｕｅｒ谱吸收峰皆由三组双峰组成，除强度不同外，其余参数均相同，可指派其结构为及此类配位结构在反应体系中分别瞬间转化为及是其具有催化活性的关键．     

近红外区N－H和O－H振动吸收谱带在定性定量分析中的应用

本研究介绍了如何应用近红外光谱对Ｎ─Ｈ、Ｏ─Ｈ等官能团进行定量分析，以及如何应用近红外光谱法研究金属氧化物的表面羟基与其催化活性的关系。